Triphenylphosphine promoted addition of acetylenic esters to benzofuran-2,3-dione: One-pot synthesis of novel γ-spirolactones

Novel One-Pot Synthesis of Pyrazolopyranopyrimidinones Using Newly Produced γ-Alumina Nanoparticles as Powerful Catalyst

g-Alumina nanoparticles (g-Al2O3 NPs) were prepared via a new and simple synthetic route and characterized by field emission scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The catalytic activity of prepared g-Al2O3 NPs was investigated for the new one-pot, ...

TiCl2/Nano-γ-Al2O3 as a Novel Lewis Acid Catalyst for Promotion of One-pot Synthesis of 1,4-dihydropyridines

Synthesis of organic compounds using nano-catalysts is more and more attention due to the numerous advantages such as cost-effectiveness, high catalytic activity, ease of product separation, recovery of the catalyst, repeated recycling potential and good stability. In this work, TiCl2/nano-γ-Al2O3, as a novel type of green heterogeneous solid acid was prepared by the immobilization of TiCl2 on ...

Choline chloride: 2 ZnCl2 catalyzed efficient one-pot regioselective synthesis of dihydrobenzofuro[2,3-b]benzofuran

The reaction of 2-naphthol and also para-substituted phenols with glyoxal in presence of choline chloride: 2 ZnCl2 [ChCl: 2ZnCl2], a deep eutectic solvent (DES), as a green catalyst was studied. The amount of catalyst, solvent type, temperature, and time on the yield of reaction were investigated. It was found that the optimal condition included 10% mol ratio of catalyst (mol percentage of DES ...

N-heterocyclic-carbene-catalyzed one-pot synthesis of hydroxamic esters.

Tin (IV) chloride-promoted one-pot synthesis of novel tacrine analogues.

A facile synthesis of potential acetylcholinesterase (AChE) inhibitors, the tacrine analogues 3a-p, has been accomplished by direct cyclocondensation of 1-aryl-4-cyano-5-aminopyrazole with β-ketoesters using tin(IV) chloride as catalyst. The structures of all the compounds have been confirmed by IR, ¹H- and ¹³C-NMR.